Asymmetric henry reaction catalyzed by chiral schiff base

Asymmetric henry reaction catalyzed by chiral schiff base

Four chiral Schiff bases were synthesized conveniently from chiral amino alcohol and 2-hydroxynaphthalene-1-carbaldehyde. These ligands were used to catalyze the addition of nitroalkanes to aldehydes under ambient conditions in good yields with up to 91% ee .

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Veröffentlicht in:Russian journal of organic chemistry 2013-06, Vol.49 (6), p.849-852
Hauptverfasser: Ran, De-qiang, Shen, Tian-hua, Zhou, Xiao-cong, Li, Jun-qi, Cui, Fu-na, Ma, Chun-an, Song, Qing-bao
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Organic Chemistry
Review
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Zusammenfassung:Four chiral Schiff bases were synthesized conveniently from chiral amino alcohol and 2-hydroxynaphthalene-1-carbaldehyde. These ligands were used to catalyze the addition of nitroalkanes to aldehydes under ambient conditions in good yields with up to 91% ee .
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428013060080