Cyclomagnesiation of nitrogen-containing 1,2-dienes with grignard compounds catalyzed by Cp2TiCl2

Cyclomagnesiation of nitrogen-containing 1,2-dienes with grignard compounds catalyzed by Cp2TiCl2

Cyclomagnesiation of nitrogen-containing 1,2-dienes with Grignard compounds in the presence of activated magnesium and Cp 2 TiCl 2 as catalyst afforded 2,5-bis(aminoalkylidene)magnesacyclopentanes in high yield.

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Veröffentlicht in:Russian journal of organic chemistry 2012-03, Vol.48 (3), p.349-353
Hauptverfasser: D’yakonov, V. A., Makarov, A. A., Makarova, E. Kh, Khalilov, L. M., Dzhemilev, U. M.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Organic Chemistry
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Zusammenfassung:Cyclomagnesiation of nitrogen-containing 1,2-dienes with Grignard compounds in the presence of activated magnesium and Cp 2 TiCl 2 as catalyst afforded 2,5-bis(aminoalkylidene)magnesacyclopentanes in high yield.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428012030025