Alkali metal 2-(1-adamantyl)ethynethiolates: Synthesis and reactions with electrophilic reagents

Treatment of ethyl 2-[1-(1-admantyl)ethylidene]hydrazine-1-carboxylate with thionyl chloride gave 4-(1-adamantyl)-1,2,3-thiadiazole which readily underwent decomposition by the action of strong bases with formation of alkali metal 2-(1-adamantyl)ethynethiolates. The latter were brought into reaction...

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Veröffentlicht in:	Russian journal of organic chemistry 2010-08, Vol.46 (8), p.1214-1218
Hauptverfasser:	Petrov, M. L, Shchipalkin, A. A, Kuznetsov, V. A, Viktorov, B. N
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Organic Chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Treatment of ethyl 2-[1-(1-admantyl)ethylidene]hydrazine-1-carboxylate with thionyl chloride gave 4-(1-adamantyl)-1,2,3-thiadiazole which readily underwent decomposition by the action of strong bases with formation of alkali metal 2-(1-adamantyl)ethynethiolates. The latter were brought into reactions with proton donors and benzyl halides.
ISSN:	1070-4280 1608-3393
DOI:	10.1134/S1070428010080166