Synthesis and application of chiral monoesters derived from cyclohex-4-ene-1,2-dicarboxylic acid and bicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic acid

Synthesis and application of chiral monoesters derived from cyclohex-4-ene-1,2-dicarboxylic acid and bicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic acid

Optically active alkyl and cycloalkyl hydrogen cyclohex-4-ene-1,2- and bicyclo[2.2.1]hept-5-ene- 2,3-dicarboxylates were synthesized by asymmetric Diels-Alder reactions in the presence of chiral catalyst. The cycloadducts were found to possess antimicrobial activity.

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Veröffentlicht in:Russian journal of organic chemistry 2008-12, Vol.44 (12), p.1756-1759
Hauptverfasser: Mamedov, E. G., Gasanov, A. G., Ayubov, I. G., Babaeva, R. Z., Gasanov, Kh. I.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Organic Chemistry
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Zusammenfassung:Optically active alkyl and cycloalkyl hydrogen cyclohex-4-ene-1,2- and bicyclo[2.2.1]hept-5-ene- 2,3-dicarboxylates were synthesized by asymmetric Diels-Alder reactions in the presence of chiral catalyst. The cycloadducts were found to possess antimicrobial activity.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428008120051