Synthesis and properties of zinc complexes of meso-hexadecyloxy-substituted tetrabenzoporphyrin and tetrabenzoazaporphyrins

The hexadecyloxyacetic acid was prepared by alkylation of glycolic acid. Proceeding from the acid obtained zinc complexes were synthesized of meso-trans -di(hexadecyloxy)tetra-benzoporphyrin, meso -tetra(hexadecyloxy)tetrabenzoporphyrin, and also of meso -hexadecyloxytetrabenzoazaporphyrins. The spe...

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Veröffentlicht in:Russian journal of organic chemistry 2008-05, Vol.44 (5), p.755-760
Hauptverfasser: Yakubov, L. A., Galanin, N. E., Shaposhnikov, G. P.
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Sprache:eng
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Zusammenfassung:The hexadecyloxyacetic acid was prepared by alkylation of glycolic acid. Proceeding from the acid obtained zinc complexes were synthesized of meso-trans -di(hexadecyloxy)tetra-benzoporphyrin, meso -tetra(hexadecyloxy)tetrabenzoporphyrin, and also of meso -hexadecyloxytetrabenzoazaporphyrins. The spectral properties of compounds synthesized were investigated.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428008050217