Continuous synthesis of organomagnesium compounds

Continuous synthesis of organomagnesium compounds

Continuous synthesis of organomagnesium compounds by the reaction of magnesium with haloalkanes RX (R = Et, n -Bu, n -Oct, c -Hex, Ph; X = Cl, Br) in a stirred column-type apparatus was studied. The effects of the solvent, solvating solvent to RX molar ratio, and temperature in the reaction zone on...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of applied chemistry 2012-04, Vol.85 (4), p.629-638
Hauptverfasser: Grachev, A. A., Klochkov, A. O., Shiryaev, V. I.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Organic Synthesis and Industrial Organic Chemistry
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Continuous synthesis of organomagnesium compounds by the reaction of magnesium with haloalkanes RX (R = Et, n -Bu, n -Oct, c -Hex, Ph; X = Cl, Br) in a stirred column-type apparatus was studied. The effects of the solvent, solvating solvent to RX molar ratio, and temperature in the reaction zone on the RX conversion and yield of organomagnesium compounds was examined.
ISSN:1070-4272
1608-3296
DOI:10.1134/S1070427212040167