Catalytic oxidation of toluene by ozone in the acetic acid-sulfuric acid system

Oxidation of toluene by ozone was studied in the system constituted by acetic and sulfuric acids in the presence of manganese(II) acetate and sodium bromide. The effect of sulfuric acid and the catalyst on the yield of benzoic acid and on the oxidation rate was considered. The optimal ozonization co...

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Veröffentlicht in:	Russian journal of applied chemistry 2011-06, Vol.84 (6), p.984-987
Hauptverfasser:	Potapenko, E. V., Andreev, P. Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Industrial Chemistry/Chemical Engineering Organic Synthesis and Industrial Organic Chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Oxidation of toluene by ozone was studied in the system constituted by acetic and sulfuric acids in the presence of manganese(II) acetate and sodium bromide. The effect of sulfuric acid and the catalyst on the yield of benzoic acid and on the oxidation rate was considered. The optimal ozonization conditions were determined. A scheme of redox catalysis that accounts for experimental data was suggested.
ISSN:	1070-4272 1608-3296
DOI:	10.1134/S1070427211060140