Zinc cadmium ammine aqua monophosphate and its thermal transformations
Synthesis of amorphous zinc cadmium ammine aqua monophosphates Zn 3− x Cd x (PO 4 ). 2 n (NH 3 ) · m (H 2 O) ( x = 0.6–2.4, n = 1.3–3.1, m = 2.3–3.4) with variable molar ratio of the cations described. The sequence of thermal transformations of compound [Zn 1.5 Cd 1.5 (NH 3 ) 1.4 (H 2 O) 3.2 (PO 4 )...
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| Veröffentlicht in: | Russian journal of applied chemistry 2008-09, Vol.81 (9), p.1492-1496 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Synthesis of amorphous zinc cadmium ammine aqua monophosphates Zn
3−
x
Cd
x
(PO
4
). 2
n
(NH
3
) ·
m
(H
2
O) (
x
= 0.6–2.4,
n
= 1.3–3.1,
m
= 2.3–3.4) with variable molar ratio of the cations described. The sequence of thermal transformations of compound [Zn
1.5
Cd
1.5
(NH
3
)
1.4
(H
2
O)
3.2
(PO
4
)
2
] with equimolar ratio of cations is studied, and schemes of its transformation into the crystalline zinc cadmium monophosphate Zn
1.5
Cd
1.5
(PO
4
)
2
are suggested. |
|---|---|
| ISSN: | 1070-4272 1608-3296 |
| DOI: | 10.1134/S1070427208090036 |