Interaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate

Interaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate

Regiochemistry of the reaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate has been studied. The possibility of alkylation at the substituted carbon atom of the triple bond of the nitrogen-containing propargyl compounds by sodium salts of acetylace...

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Veröffentlicht in:Russian journal of general chemistry 2016-05, Vol.86 (5), p.1011-1016
Hauptverfasser: Hobosyan, N. G., Balyan, K. V., Nersisyan, H. S., Sargsyan, H. B., Chobanyan, Zh. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Zusammenfassung:Regiochemistry of the reaction of nitrogen-containing propargyl compounds with CH-acids in the presence of mercury(II) acetate has been studied. The possibility of alkylation at the substituted carbon atom of the triple bond of the nitrogen-containing propargyl compounds by sodium salts of acetylacetone and acetoacetic ester with the formation of prototropic isomers has been shown.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363216050042