Protolytic and complexation properties of the cyclic thiosemicarbazone ligand

The acid-base properties of the thiourea based cyclic thiosemicarbazone have been studied. The tautomerism and complex formation ability of the thiosemicarbazone were investigated by the methods of quantum chemistry and electronic spectroscopy. The complexes of copper(II), nickel(II), cobalt(II), an...

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Veröffentlicht in:	Russian journal of general chemistry 2015, Vol.85 (1), p.92-96
Hauptverfasser:	Popov, L. D., Gazieva, G. A., Kravchenko, A. N., Tkachenko, Yu. N., Askalepova, O. I., Levchenkov, S. I., Karpova, T. B., Tupolova, Yu. P., Kogan, V. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science
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Zusammenfassung:	The acid-base properties of the thiourea based cyclic thiosemicarbazone have been studied. The tautomerism and complex formation ability of the thiosemicarbazone were investigated by the methods of quantum chemistry and electronic spectroscopy. The complexes of copper(II), nickel(II), cobalt(II), and mercury(II) were synthesized and their structure suggested.
ISSN:	1070-3632 1608-3350
DOI:	10.1134/S1070363215010168