Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane
Physicochemical properties of new isostructural homo- and heteronuclear coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane (H 2 L) differing in the composition have been studied. The Tb 2 L 3 ·H 2 O compound has exhibited efficient sensibili...
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| Veröffentlicht in: | Russian journal of general chemistry 2014-10, Vol.84 (10), p.1994-2000 |
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| container_end_page | 2000 |
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| container_issue | 10 |
| container_start_page | 1994 |
| container_title | Russian journal of general chemistry |
| container_volume | 84 |
| creator | Zseltvay, I. I. Meshkova, S. B. Novikova, N. S. Kondrat’eva, R. V. Nedostup, V. I. Doga, P. G. Skripinets, Yu. V. Zhikhareva, E. A. |
| description | Physicochemical properties of new isostructural homo- and heteronuclear coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane (H
2
L) differing in the composition have been studied. The Tb
2
L
3
·H
2
O compound has exhibited efficient sensibilized green luminescence, whereas the corresponding europium-containing polymer EuL
3
·H
2
O has shown practically no luminescence due to mismatch of energies of the ligand triplet level and the Eu
3+
ion emitting level. Heteronuclear terbium-europium polymers (Tb
1.5
Eu
0.5
L
3
·H
2
O, TbEuL
3
·H
2
O, and Tb
0.5
Eu
1.5
L
3
·H
2
O) show luminescence via the intramolecular transfer of the exiting energy from Tb
3+
emitting level to Eu
3+
. |
| doi_str_mv | 10.1134/S1070363214100223 |
| format | Article |
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2
L) differing in the composition have been studied. The Tb
2
L
3
·H
2
O compound has exhibited efficient sensibilized green luminescence, whereas the corresponding europium-containing polymer EuL
3
·H
2
O has shown practically no luminescence due to mismatch of energies of the ligand triplet level and the Eu
3+
ion emitting level. Heteronuclear terbium-europium polymers (Tb
1.5
Eu
0.5
L
3
·H
2
O, TbEuL
3
·H
2
O, and Tb
0.5
Eu
1.5
L
3
·H
2
O) show luminescence via the intramolecular transfer of the exiting energy from Tb
3+
emitting level to Eu
3+
.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363214100223</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science</subject><ispartof>Russian journal of general chemistry, 2014-10, Vol.84 (10), p.1994-2000</ispartof><rights>Pleiades Publishing, Ltd. 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c240t-22bb15c77df77c48f12ded07b25f98600652315b739825555d4065c3db035ae23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363214100223$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363214100223$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Zseltvay, I. I.</creatorcontrib><creatorcontrib>Meshkova, S. B.</creatorcontrib><creatorcontrib>Novikova, N. S.</creatorcontrib><creatorcontrib>Kondrat’eva, R. V.</creatorcontrib><creatorcontrib>Nedostup, V. I.</creatorcontrib><creatorcontrib>Doga, P. G.</creatorcontrib><creatorcontrib>Skripinets, Yu. V.</creatorcontrib><creatorcontrib>Zhikhareva, E. A.</creatorcontrib><title>Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>Physicochemical properties of new isostructural homo- and heteronuclear coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane (H
2
L) differing in the composition have been studied. The Tb
2
L
3
·H
2
O compound has exhibited efficient sensibilized green luminescence, whereas the corresponding europium-containing polymer EuL
3
·H
2
O has shown practically no luminescence due to mismatch of energies of the ligand triplet level and the Eu
3+
ion emitting level. Heteronuclear terbium-europium polymers (Tb
1.5
Eu
0.5
L
3
·H
2
O, TbEuL
3
·H
2
O, and Tb
0.5
Eu
1.5
L
3
·H
2
O) show luminescence via the intramolecular transfer of the exiting energy from Tb
3+
emitting level to Eu
3+
.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKxDAUhoMoOI4-gLsuFYzm0svMUgZvMKCgrksupzZDm5QkRfskvq4Zx4UgmM1J_v__DjkHoVNKLinl-dUzJRXhJWc0p4QwxvfQjJZkgTkvyH66Jxtv_UN0FMKGkJQq2Qx9PnkYhBfROJsJq7Nu7I2FoMDGbPBuAB8NhMw1mXLOa2N30cF1Uw_-24jgpRn7bxzGxGwf7ya2Gb3IsTQBn-W4h9i6j0kJL52dOsxxO2mflKEF-8s4l2MUFo7RQSO6ACc_dY5eb29eVvd4_Xj3sLpeY8VyEjFjUtJCVZVuqkrli4YyDZpUkhXNclGmGQvGaSErvlywIh2dJ0lxLQkvBDA-R3TXV3kXgoemHrzphZ9qSurtZus_m00M2zEhZe0b-HrjRm_TN_-BvgBacn3U</recordid><startdate>20141001</startdate><enddate>20141001</enddate><creator>Zseltvay, I. I.</creator><creator>Meshkova, S. B.</creator><creator>Novikova, N. S.</creator><creator>Kondrat’eva, R. V.</creator><creator>Nedostup, V. I.</creator><creator>Doga, P. G.</creator><creator>Skripinets, Yu. V.</creator><creator>Zhikhareva, E. A.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20141001</creationdate><title>Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane</title><author>Zseltvay, I. I. ; Meshkova, S. B. ; Novikova, N. S. ; Kondrat’eva, R. V. ; Nedostup, V. I. ; Doga, P. G. ; Skripinets, Yu. V. ; Zhikhareva, E. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-22bb15c77df77c48f12ded07b25f98600652315b739825555d4065c3db035ae23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zseltvay, I. I.</creatorcontrib><creatorcontrib>Meshkova, S. B.</creatorcontrib><creatorcontrib>Novikova, N. S.</creatorcontrib><creatorcontrib>Kondrat’eva, R. V.</creatorcontrib><creatorcontrib>Nedostup, V. I.</creatorcontrib><creatorcontrib>Doga, P. G.</creatorcontrib><creatorcontrib>Skripinets, Yu. V.</creatorcontrib><creatorcontrib>Zhikhareva, E. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zseltvay, I. I.</au><au>Meshkova, S. B.</au><au>Novikova, N. S.</au><au>Kondrat’eva, R. V.</au><au>Nedostup, V. I.</au><au>Doga, P. G.</au><au>Skripinets, Yu. V.</au><au>Zhikhareva, E. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2014-10-01</date><risdate>2014</risdate><volume>84</volume><issue>10</issue><spage>1994</spage><epage>2000</epage><pages>1994-2000</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>Physicochemical properties of new isostructural homo- and heteronuclear coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane (H
2
L) differing in the composition have been studied. The Tb
2
L
3
·H
2
O compound has exhibited efficient sensibilized green luminescence, whereas the corresponding europium-containing polymer EuL
3
·H
2
O has shown practically no luminescence due to mismatch of energies of the ligand triplet level and the Eu
3+
ion emitting level. Heteronuclear terbium-europium polymers (Tb
1.5
Eu
0.5
L
3
·H
2
O, TbEuL
3
·H
2
O, and Tb
0.5
Eu
1.5
L
3
·H
2
O) show luminescence via the intramolecular transfer of the exiting energy from Tb
3+
emitting level to Eu
3+
.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363214100223</doi><tpages>7</tpages></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science |
| title | Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane |
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