Synthesis, X-ray structure, and stevens rearrangement of 1,1-di(prop-2-yn-1-yl)-2,5-dihydro-1H-pyrrol-1-ium bromide

Synthesis, X-ray structure, and stevens rearrangement of 1,1-di(prop-2-yn-1-yl)-2,5-dihydro-1H-pyrrol-1-ium bromide

1,1-Di(prop-2-yn-1-yl)-2,5-dihydro-1 H -Pyrrol-1-ium bromide was obtained with interaction of 3-pyrroline with propargyl bromide and its structure was studied by X-ray analysis. It has been shown that the Stevens rearrangement of obtaining salt leads to the formation of 1-(hexa-4,5-dien-1-yn-3-yl)-2...

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Veröffentlicht in:Russian journal of general chemistry 2014-10, Vol.84 (10), p.1938-1940
Hauptverfasser: Gyul’nazaryan, A. Kh, Sahakyan, T. A., Sargsyan, G. T., Grigoryan, J. V., Aivazyan, A. G., Tamanyan, R. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Zusammenfassung:1,1-Di(prop-2-yn-1-yl)-2,5-dihydro-1 H -Pyrrol-1-ium bromide was obtained with interaction of 3-pyrroline with propargyl bromide and its structure was studied by X-ray analysis. It has been shown that the Stevens rearrangement of obtaining salt leads to the formation of 1-(hexa-4,5-dien-1-yn-3-yl)-2,5-dihydro-1 H -pyrrol.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363214100132