Efficient racemization of 1-phenylethylamine and its derivatives
We report on simple and efficient procedure for the racemization of 1-phenylethylamine and its derivatives. In the presence of trichloroisocyanuric acid, N -chloroimine derivative is formed as the intermediates, with subsequent hydrogenation catalyzed by Pd-C leading to the racemic product.
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| Veröffentlicht in: | Russian journal of general chemistry 2013-12, Vol.83 (12), p.2402-2405 |
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| container_issue | 12 |
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| container_title | Russian journal of general chemistry |
| container_volume | 83 |
| creator | Xiong, Xiaoxia Xu, Xinliang Zhou, Yifeng Weng, Chenchen |
| description | We report on simple and efficient procedure for the racemization of 1-phenylethylamine and its derivatives. In the presence of trichloroisocyanuric acid,
N
-chloroimine derivative is formed as the intermediates, with subsequent hydrogenation catalyzed by Pd-C leading to the racemic product. |
| doi_str_mv | 10.1134/S1070363213120359 |
| format | Article |
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N
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| identifier | ISSN: 1070-3632 |
| ispartof | Russian journal of general chemistry, 2013-12, Vol.83 (12), p.2402-2405 |
| issn | 1070-3632 1608-3350 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S1070363213120359 |
| source | SpringerNature Journals |
| subjects | Chemistry Chemistry and Materials Science Chemistry/Food Science |
| title | Efficient racemization of 1-phenylethylamine and its derivatives |
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