Efficient racemization of 1-phenylethylamine and its derivatives

We report on simple and efficient procedure for the racemization of 1-phenylethylamine and its derivatives. In the presence of trichloroisocyanuric acid, N -chloroimine derivative is formed as the intermediates, with subsequent hydrogenation catalyzed by Pd-C leading to the racemic product.

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Bibliographische Detailangaben
Veröffentlicht in:	Russian journal of general chemistry 2013-12, Vol.83 (12), p.2402-2405
Hauptverfasser:	Xiong, Xiaoxia, Xu, Xinliang, Zhou, Yifeng, Weng, Chenchen
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	We report on simple and efficient procedure for the racemization of 1-phenylethylamine and its derivatives. In the presence of trichloroisocyanuric acid, N -chloroimine derivative is formed as the intermediates, with subsequent hydrogenation catalyzed by Pd-C leading to the racemic product.
ISSN:	1070-3632 1608-3350
DOI:	10.1134/S1070363213120359