Solution-solid phase equilibrium in the systems copper(II) halide-aprotic organic solvent-water

Solution-solid phase equilibrium in the systems copper(II) halide-aprotic organic solvent-water

In the study of the solution-solid phase equilibrium in CuX 2 -S-H 2 O system (X = Cl, Br, S = dimethyl sulfoxide, N , N -dimethylformamide, tetrahydrofuran, 1,4-dioxane) at 25°C we established the effect of the solvent properties and the type of the halide ligand (dielectric premeability, donor num...

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Veröffentlicht in:Russian journal of general chemistry 2012-06, Vol.82 (6), p.1053-1057
Hauptverfasser: Gorbunov, A. O., Spektor, K. K., Skripkin, M. Yu, Tsyrulnikov, N. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Zusammenfassung:In the study of the solution-solid phase equilibrium in CuX 2 -S-H 2 O system (X = Cl, Br, S = dimethyl sulfoxide, N , N -dimethylformamide, tetrahydrofuran, 1,4-dioxane) at 25°C we established the effect of the solvent properties and the type of the halide ligand (dielectric premeability, donor number, hydrophobicity) on the solubility of the solid phase in binary and ternary systems, the length of the fields of crystallization of the compounds and the structure of the water-organic solvates.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363212060023