Oxidation of 6-methyl-2,4-dioxypyrimidine with selenious acid
The yield orotic aldehyde at the oxidation of 6-methyl-2,4-dihydroxypyrimidine was found to increase when selenious acid is used as an oxidizer. A comparative analysis of 6-methyl-2,4-dioxypyrimidine oxidation with selenium dioxide and selenious acid was performed using the ab initio quantum chemica...
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| Veröffentlicht in: | Russian journal of general chemistry 2011-11, Vol.81 (11), p.2328-2331 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | The yield orotic aldehyde at the oxidation of 6-methyl-2,4-dihydroxypyrimidine was found to increase when selenious acid is used as an oxidizer. A comparative analysis of 6-methyl-2,4-dioxypyrimidine oxidation with selenium dioxide and selenious acid was performed using the
ab initio
quantum chemical method in the 6-31G** basis. |
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| ISSN: | 1070-3632 1608-3350 |
| DOI: | 10.1134/S1070363211110181 |