Reactions of C-phosphorylated acetamidines with dialkylchlorophosphates

The reactions of the C-phosphorylated acetamidines sodium derivatives with dialkylchlorophosphates were studied. They occur selectively to afford N 1 , N 1 -dialkyl- N 2 -benzoylbis(dialkoxyphosphoryl)-acetamidines. Based on the CH-acid properties of C-phosphorylated acetamidines, we developed a con...

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Veröffentlicht in:	Russian journal of general chemistry 2011-04, Vol.81 (4), p.639-641
Hauptverfasser:	Shishkin, V. E., Mednikov, E. V., Popov, Yu. V., Shevchenko, M. A., Anishchenko, O. V., Gurba, E. V., Bang, Chau Nhat, Emenka, B. D.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science
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Zusammenfassung:	The reactions of the C-phosphorylated acetamidines sodium derivatives with dialkylchlorophosphates were studied. They occur selectively to afford N 1 , N 1 -dialkyl- N 2 -benzoylbis(dialkoxyphosphoryl)-acetamidines. Based on the CH-acid properties of C-phosphorylated acetamidines, we developed a convenient method for the synthesis of new diphosphorylated amidines.
ISSN:	1070-3632 1608-3350
DOI:	10.1134/S1070363211040037