Parameters of electrical double layer on the boundary copper electrode/water-organic solution of copper sulfate

By the method of impedance spectroscopy the properties of the phase boundary of Cu|H 2 O + i -C 3 H 7 OH + CuSO 4 system were investigated. The impedance hodographs were obtained, in the form of circles with displaced centers. The capacity values of electrical double layer, exchange currents, and re...

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Veröffentlicht in:Russian journal of general chemistry 2009-11, Vol.79 (11), p.2287-2292
Hauptverfasser: Kuz’min, S. M., Chulovskaya, S. A., Noskov, A. V., Parfenyuk, V. I.
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Sprache:eng
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Zusammenfassung:By the method of impedance spectroscopy the properties of the phase boundary of Cu|H 2 O + i -C 3 H 7 OH + CuSO 4 system were investigated. The impedance hodographs were obtained, in the form of circles with displaced centers. The capacity values of electrical double layer, exchange currents, and resistance of the electrolyte solution depending on the mole fraction of 2-propanol were determined. The role of organic component in the formation of the electrical double layer in the studied system is elucidated.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363209110024