Oxidative dimerization of methane: Kinetics, mathematical modeling, and optimization with La/Ce catalysts

Oxidative dimerization of methane: Kinetics, mathematical modeling, and optimization with La/Ce catalysts

Kinetic features of oxidative dimerization of methane to ethane and ethylene, catalyzed by a mixture of lanthanum and cerium oxides deposited onto a magnesium oxide support, were examined. A kinetic model was proposed, and the process optimization was performed for a plug-flow reactor in the quasi-h...

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Veröffentlicht in:Russian journal of general chemistry 2009-09, Vol.79 (9), p.2016-2023
Hauptverfasser: Makhlin, V. A., Podlesnaya, M. V., Dedov, A. G., Loktev, A. S., Tel’pukhovskaya, N. O., Moiseev, I. I.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
New Materials
Processes
Technologies
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Zusammenfassung:Kinetic features of oxidative dimerization of methane to ethane and ethylene, catalyzed by a mixture of lanthanum and cerium oxides deposited onto a magnesium oxide support, were examined. A kinetic model was proposed, and the process optimization was performed for a plug-flow reactor in the quasi-homogeneous approximation.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363209090333