Erbium and ytterbium complexes with the phtalocyanines with aryloxy and chlorine substituents

By nucleophilic substitution of chlorine atoms in tetrachlorophthalonitrile by phenoxy- or 1-naphthyloxy groups aryloxychlorophthalonitriles were synthesized and on this basis respective substituted erbium and ytterbium phthalocyanines with chloro-, acetate- or acetylacetonate anions as extra ligand...

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Veröffentlicht in:Russian journal of general chemistry 2009-08, Vol.79 (8), p.1728-1734
Hauptverfasser: Kulinich, V. P., Lebedeva, T. A., Borisov, A. V., Gorelov, V. N., Shaposhnikov, G. P.
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Sprache:eng
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Zusammenfassung:By nucleophilic substitution of chlorine atoms in tetrachlorophthalonitrile by phenoxy- or 1-naphthyloxy groups aryloxychlorophthalonitriles were synthesized and on this basis respective substituted erbium and ytterbium phthalocyanines with chloro-, acetate- or acetylacetonate anions as extra ligands. The compounds obtained were characterized by elemental analysis, chromato-mass spectrometry, IR, 13 C NMR, and electronic spectroscopy.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363209080258