Some aspects of quantum-chemical study of the mercuriation of organophosphorus compounds

Quantum-chemical investigation of possible intermediate steps in the mercuriation of arylphosphines was performed. Effect of the anion nature on the facility of ylide formation from arylphosphonium salts, the limiting step of the mercuriation, is considered.

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Bibliographische Detailangaben
Veröffentlicht in:	Russian journal of general chemistry 2008-12, Vol.78 (12), p.2330-2332
Hauptverfasser:	Nevstruev, A. N., Laskatelev, E. V., Samoilov, S. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Quantum-chemical investigation of possible intermediate steps in the mercuriation of arylphosphines was performed. Effect of the anion nature on the facility of ylide formation from arylphosphonium salts, the limiting step of the mercuriation, is considered.
ISSN:	1070-3632 1608-3350
DOI:	10.1134/S1070363208120062