Reversible Phase Transition in the MoO2Cl2(DME) Structure with the Retention of the Crystal System and Space Group

Reversible Phase Transition in the MoO2Cl2(DME) Structure with the Retention of the Crystal System and Space Group

A completely reversible phase transition in the MoO 2 Cl 2 (DME) compound with the retention of the crystal system and space group is discovered and studied. The transition is also accompanied by the doubling of the unit cell parameter and occurs without single crystal destruction. The crystal struc...

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Veröffentlicht in:Russian journal of coordination chemistry 2020-12, Vol.46 (12), p.812-816
Hauptverfasser: Churakov, A. V., Rufanov, K. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
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Zusammenfassung:A completely reversible phase transition in the MoO 2 Cl 2 (DME) compound with the retention of the crystal system and space group is discovered and studied. The transition is also accompanied by the doubling of the unit cell parameter and occurs without single crystal destruction. The crystal structure of the MoO 2 Cl 2 (DME) complex are determined at 160 (modification I ) and 150 K (modification II ) (CIF files CCDC nos. 1997752 and 1997751, respectively).
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328420110020