Synthesis, structure, and properties of the complex [Cu(L)Cl] ∙ 2H2O
The crystal structure of copper(II) complex with the HL ligand obtained from 3-[4-carboxyphenylazo] penta-2,4-dione and ethylenediamine (En) was determined by X-ray diffraction. The crystals are orthorhombic: a = 7.329(3), b = 15.393(5), c = 18.474(7) Å, V = 2084.1(12) Å 3 , space group P 2 1 2 1 2...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2016-05, Vol.42 (5), p.351-354 |
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| container_title | Russian journal of coordination chemistry |
| container_volume | 42 |
| creator | Magerramov, A. M. Tsintsadze, G. V. Alieva, R. A. Mamedova, F. O. Alieva, F. S. Bakhmanova, F. N. Kurbanov, A. V. Chyragov, F. M. |
| description | The crystal structure of copper(II) complex with the HL ligand obtained from 3-[4-carboxyphenylazo] penta-2,4-dione and ethylenediamine (En) was determined by X-ray diffraction. The crystals are orthorhombic:
a
= 7.329(3),
b
= 15.393(5),
c
= 18.474(7) Å,
V
= 2084.1(12) Å
3
, space group
P
2
1
2
1
2
1
,
Z
= 4, ρ
(calcd.)
= 1.486 g/cm
3
,
R
= 0.0441. The copper atom is coordinated by four nitrogen atoms of two En ligands and by the chlorine atom in an axial position according to the extended square pyramid geometry (4 + 1) (CIF file CCDC no. 1436882). |
| doi_str_mv | 10.1134/S1070328416050043 |
| format | Article |
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a
= 7.329(3),
b
= 15.393(5),
c
= 18.474(7) Å,
V
= 2084.1(12) Å
3
, space group
P
2
1
2
1
2
1
,
Z
= 4, ρ
(calcd.)
= 1.486 g/cm
3
,
R
= 0.0441. The copper atom is coordinated by four nitrogen atoms of two En ligands and by the chlorine atom in an axial position according to the extended square pyramid geometry (4 + 1) (CIF file CCDC no. 1436882).</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328416050043</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2016-05, Vol.42 (5), p.351-354</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1553-f837fd4c3e3c9c2f253604ec31c23f224821ead5bf37c207405fda2ba313cead3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328416050043$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328416050043$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Magerramov, A. M.</creatorcontrib><creatorcontrib>Tsintsadze, G. V.</creatorcontrib><creatorcontrib>Alieva, R. A.</creatorcontrib><creatorcontrib>Mamedova, F. O.</creatorcontrib><creatorcontrib>Alieva, F. S.</creatorcontrib><creatorcontrib>Bakhmanova, F. N.</creatorcontrib><creatorcontrib>Kurbanov, A. V.</creatorcontrib><creatorcontrib>Chyragov, F. M.</creatorcontrib><title>Synthesis, structure, and properties of the complex [Cu(L)Cl] ∙ 2H2O</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>The crystal structure of copper(II) complex with the HL ligand obtained from 3-[4-carboxyphenylazo] penta-2,4-dione and ethylenediamine (En) was determined by X-ray diffraction. The crystals are orthorhombic:
a
= 7.329(3),
b
= 15.393(5),
c
= 18.474(7) Å,
V
= 2084.1(12) Å
3
, space group
P
2
1
2
1
2
1
,
Z
= 4, ρ
(calcd.)
= 1.486 g/cm
3
,
R
= 0.0441. The copper atom is coordinated by four nitrogen atoms of two En ligands and by the chlorine atom in an axial position according to the extended square pyramid geometry (4 + 1) (CIF file CCDC no. 1436882).</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp9kMFKw0AURQdRsFY_wN0sFRp9b95Mky4lWCsEuqiuREI6mdGUNAkzCdg_8Bf8Pb_EKXUnuHoXzr2Xx2XsEuEGkeTtCiEGEonEKSgASUdsFGQSEWFyHHTA0Z6fsjPvNwAIoGYjNl_tmv7d-MpPuO_doPvBmQkvmpJ3ru2M6yvjeWt5MHHdbrvafPCXdLjKrtP6lX9_fnGxEMtzdmKL2puL3ztmz_P7p3QRZcuHx_QuizQqRZFNKLal1GRIz7SwQtEUpNGEWpAVQiYCTVGqtaVYC4glKFsWYl0Qkg6AxgwPvdq13jtj885V28LtcoR8P0T-Z4iQEYeMD97mzbh80w6uCW_-E_oBPlRezQ</recordid><startdate>20160501</startdate><enddate>20160501</enddate><creator>Magerramov, A. M.</creator><creator>Tsintsadze, G. V.</creator><creator>Alieva, R. A.</creator><creator>Mamedova, F. O.</creator><creator>Alieva, F. S.</creator><creator>Bakhmanova, F. N.</creator><creator>Kurbanov, A. V.</creator><creator>Chyragov, F. M.</creator><general>Pleiades Publishing</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160501</creationdate><title>Synthesis, structure, and properties of the complex [Cu(L)Cl] ∙ 2H2O</title><author>Magerramov, A. M. ; Tsintsadze, G. V. ; Alieva, R. A. ; Mamedova, F. O. ; Alieva, F. S. ; Bakhmanova, F. N. ; Kurbanov, A. V. ; Chyragov, F. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1553-f837fd4c3e3c9c2f253604ec31c23f224821ead5bf37c207405fda2ba313cead3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Magerramov, A. M.</creatorcontrib><creatorcontrib>Tsintsadze, G. V.</creatorcontrib><creatorcontrib>Alieva, R. A.</creatorcontrib><creatorcontrib>Mamedova, F. O.</creatorcontrib><creatorcontrib>Alieva, F. S.</creatorcontrib><creatorcontrib>Bakhmanova, F. N.</creatorcontrib><creatorcontrib>Kurbanov, A. V.</creatorcontrib><creatorcontrib>Chyragov, F. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Magerramov, A. M.</au><au>Tsintsadze, G. V.</au><au>Alieva, R. A.</au><au>Mamedova, F. O.</au><au>Alieva, F. S.</au><au>Bakhmanova, F. N.</au><au>Kurbanov, A. V.</au><au>Chyragov, F. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, structure, and properties of the complex [Cu(L)Cl] ∙ 2H2O</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2016-05-01</date><risdate>2016</risdate><volume>42</volume><issue>5</issue><spage>351</spage><epage>354</epage><pages>351-354</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>The crystal structure of copper(II) complex with the HL ligand obtained from 3-[4-carboxyphenylazo] penta-2,4-dione and ethylenediamine (En) was determined by X-ray diffraction. The crystals are orthorhombic:
a
= 7.329(3),
b
= 15.393(5),
c
= 18.474(7) Å,
V
= 2084.1(12) Å
3
, space group
P
2
1
2
1
2
1
,
Z
= 4, ρ
(calcd.)
= 1.486 g/cm
3
,
R
= 0.0441. The copper atom is coordinated by four nitrogen atoms of two En ligands and by the chlorine atom in an axial position according to the extended square pyramid geometry (4 + 1) (CIF file CCDC no. 1436882).</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328416050043</doi><tpages>4</tpages></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Physical Chemistry |
| title | Synthesis, structure, and properties of the complex [Cu(L)Cl] ∙ 2H2O |
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