Synthesis, structure, and properties of the complex [Cu(L)Cl] ∙ 2H2O

The crystal structure of copper(II) complex with the HL ligand obtained from 3-[4-carboxyphenylazo] penta-2,4-dione and ethylenediamine (En) was determined by X-ray diffraction. The crystals are orthorhombic: a = 7.329(3), b = 15.393(5), c = 18.474(7) Å, V = 2084.1(12) Å 3 , space group P 2 1 2 1 2...

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Veröffentlicht in:Russian journal of coordination chemistry 2016-05, Vol.42 (5), p.351-354
Hauptverfasser: Magerramov, A. M., Tsintsadze, G. V., Alieva, R. A., Mamedova, F. O., Alieva, F. S., Bakhmanova, F. N., Kurbanov, A. V., Chyragov, F. M.
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Sprache:eng
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Zusammenfassung:The crystal structure of copper(II) complex with the HL ligand obtained from 3-[4-carboxyphenylazo] penta-2,4-dione and ethylenediamine (En) was determined by X-ray diffraction. The crystals are orthorhombic: a = 7.329(3), b = 15.393(5), c = 18.474(7) Å, V = 2084.1(12) Å 3 , space group P 2 1 2 1 2 1 , Z = 4, ρ (calcd.) = 1.486 g/cm 3 , R = 0.0441. The copper atom is coordinated by four nitrogen atoms of two En ligands and by the chlorine atom in an axial position according to the extended square pyramid geometry (4 + 1) (CIF file CCDC no. 1436882).
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328416050043