Crystal and molecular structures of tetraaqua(di-para-oxybenzoato)iron(II) tetrahydrate

Crystal and molecular structures of tetraaqua(di-para-oxybenzoato)iron(II) tetrahydrate

The new complex [( p -HOC 6 H 4 CO 2 ) 2 Fe(H 2 O) 4 ] · 4H 2 O is synthesized and studied by X-ray diffraction analysis. The Fe(II) cation is coordinated by two para -hydroxybenzoate anions through the mono-dentate mode. Four oxygen atoms of the water molecules complete the coordination polyhedron...

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Veröffentlicht in:Russian journal of coordination chemistry 2010, Vol.36 (1), p.73-75
Hauptverfasser: Mamedova, A. T., Rzaeva, M. F., Movsumov, E. M., Sergienko, V. S.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Physical Chemistry
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Zusammenfassung:The new complex [( p -HOC 6 H 4 CO 2 ) 2 Fe(H 2 O) 4 ] · 4H 2 O is synthesized and studied by X-ray diffraction analysis. The Fe(II) cation is coordinated by two para -hydroxybenzoate anions through the mono-dentate mode. Four oxygen atoms of the water molecules complete the coordination polyhedron of the central atom to an octahedron. Four molecules of water of crystallization “cross-link” the monomers to form a polymeric structure.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328410010124