Synthesis of spiropyran analogues of retinal and study of their interaction with bacterioopsin from Halobacterium salinarum

Synthesis of spiropyran analogues of retinal and study of their interaction with bacterioopsin from Halobacterium salinarum

The synthesis of a series of retinal analogues containing the spiropyran moiety instead of trimethylcyclohexene ring was proposed. The interaction of the resulting retinal analogues with bacterioopsin from apomembranes of Halobacterium salinarum and the spectral characteristics of the new pigments w...

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Veröffentlicht in:Russian journal of bioorganic chemistry 2008, Vol.34 (2), p.252-260
Hauptverfasser: Laptev, A. V, Belikov, N. E, Lukin, A. Yu, Strokach, Yu. P, Barachevsky, V. A, Alfimov, M. V, Demina, O. V, Shvets, V. I, Skladnev, D. A, Khodonov, A. A
Format: Artikel
Sprache:eng
Schlagworte:
bacteriorhodopsin
Biochemistry
Biomedical and Life Sciences
Biomedicine
Bioorganic Chemistry
Life Sciences
Organic Chemistry
photochromic compounds
retinal analogues
spiropyrans
the Horner-Emmons olefination
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Zusammenfassung:The synthesis of a series of retinal analogues containing the spiropyran moiety instead of trimethylcyclohexene ring was proposed. The interaction of the resulting retinal analogues with bacterioopsin from apomembranes of Halobacterium salinarum and the spectral characteristics of the new pigments were studied.
ISSN:1068-1620
1608-330X
1573-9163
DOI:10.1134/S1068162008020179