High cadmium-109 recovery from a dissolved silver target solution using dowex 1×8 anion-exchange resin

Separation of 109 Cd produced by proton irradiation of a silver target from the target material and the other products was achieved. Radiochemical separation of 109 Cd from silver and nonisotopic impurities involves two steps: precipitation and ion exchange. The dissolved target material solution is...

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Veröffentlicht in:Radiochemistry (New York, N.Y.) N.Y.), 2010-10, Vol.52 (5), p.565-569
Hauptverfasser: Sadeghi, M., Mirzaii, M., Gholamzadeh, Z., Sarabadani, P., Sattari, A.
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container_issue 5
container_start_page 565
container_title Radiochemistry (New York, N.Y.)
container_volume 52
creator Sadeghi, M.
Mirzaii, M.
Gholamzadeh, Z.
Sarabadani, P.
Sattari, A.
description Separation of 109 Cd produced by proton irradiation of a silver target from the target material and the other products was achieved. Radiochemical separation of 109 Cd from silver and nonisotopic impurities involves two steps: precipitation and ion exchange. The dissolved target material solution is evaporated almost to dryness. The residue is dissolved in 0.015 M HCl, with quantitative precipitation of silver from the solution. In the second step, 109 Cd is separated from Cu and 65 Zn on an anion-exchange column (Dowex 1×8). 109 Cd is completely retained in the column, whereas copper and more than 70% of 65 Zn pass through during loading the solution. 109 Cd is then eluted from the column with 0.5 M HNO 3 . High recovery of 109 Cd (99.77%) with 2.1% 65 Zn impurity was attained.
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Radiochemical separation of 109 Cd from silver and nonisotopic impurities involves two steps: precipitation and ion exchange. The dissolved target material solution is evaporated almost to dryness. The residue is dissolved in 0.015 M HCl, with quantitative precipitation of silver from the solution. In the second step, 109 Cd is separated from Cu and 65 Zn on an anion-exchange column (Dowex 1×8). 109 Cd is completely retained in the column, whereas copper and more than 70% of 65 Zn pass through during loading the solution. 109 Cd is then eluted from the column with 0.5 M HNO 3 . 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Chemistry and Materials Science
Chemistry/Food Science
Nuclear Chemistry
title High cadmium-109 recovery from a dissolved silver target solution using dowex 1×8 anion-exchange resin
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