High cadmium-109 recovery from a dissolved silver target solution using dowex 1×8 anion-exchange resin
Separation of 109 Cd produced by proton irradiation of a silver target from the target material and the other products was achieved. Radiochemical separation of 109 Cd from silver and nonisotopic impurities involves two steps: precipitation and ion exchange. The dissolved target material solution is...
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Veröffentlicht in: | Radiochemistry (New York, N.Y.) N.Y.), 2010-10, Vol.52 (5), p.565-569 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Separation of
109
Cd produced by proton irradiation of a silver target from the target material and the other products was achieved. Radiochemical separation of
109
Cd from silver and nonisotopic impurities involves two steps: precipitation and ion exchange. The dissolved target material solution is evaporated almost to dryness. The residue is dissolved in 0.015 M HCl, with quantitative precipitation of silver from the solution. In the second step,
109
Cd is separated from Cu and
65
Zn on an anion-exchange column (Dowex 1×8).
109
Cd is completely retained in the column, whereas copper and more than 70% of
65
Zn pass through during loading the solution.
109
Cd is then eluted from the column with 0.5 M HNO
3
. High recovery of
109
Cd (99.77%) with 2.1%
65
Zn impurity was attained. |
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ISSN: | 1066-3622 1608-3288 |
DOI: | 10.1134/S1066362210050218 |