Modification of water, aqueous solutions, and dielectric films in diffuse discharge formed by fast electron preionization at the short front of a voltage pulse

Formation of a diffuse discharge at a short front of voltage pulse (less than 1 ns), as well as when placing water, water solutions, and dielectric film inside the discharge, is studied. A volumetric discharge was observed in water on the anode when placing dielectric film (polyethylene, vinyl chloride-methyl methacrylate (VCMMA), etc.), water, or aqueous solutions of 3% hydrogen dioxide or 18% KMgO 4 inside the discharge. The change in the absorption spectrum of substance was found after multiple discharge switching on. Fourier analysis of the infrared absorption spectra showed the difference between the spectra of exposed and unexposed polyethylene film. The changes in the absorption spectra of water, 3% hydrogen dioxide and 18% KMgO 4 aqueous solutions are related with expansion of the band of valence oscillations of OH-groups without clearly expressed maxima (for the studied liquids). Therefore, volumetric diffuse discharge in molecular and atomic gases can be used in modifying dielectrics, water and aqueous solutions.