Gadolinium ion localization in RbPb2Cl5 crystals

The spectrum of the electron paramagnetic resonance of high-spin triclinic Gd 3+ centers in lead-rubidium chloride single crystals has been studied. The spin Hamiltonian parameters have been determined. It has been concluded that the rare-earth ion is localized at the lead site whose environment is...

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Veröffentlicht in:Physics of the solid state 2012-06, Vol.54 (6), p.1249-1253
Hauptverfasser: Vazhenin, V. A., Potapov, A. P., Ivachev, A. N., Artyomov, M. Yu, Guseva, V. B.
Format: Artikel
Sprache:eng
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Zusammenfassung:The spectrum of the electron paramagnetic resonance of high-spin triclinic Gd 3+ centers in lead-rubidium chloride single crystals has been studied. The spin Hamiltonian parameters have been determined. It has been concluded that the rare-earth ion is localized at the lead site whose environment is a tricapped trigonal prism.
ISSN:1063-7834
1090-6460
DOI:10.1134/S1063783412060352