Effect of the method for the preparation of the oxide precursor on the electrolytic properties of sulfide-conducting solid electrolytes

Effect of the method for the preparation of the oxide precursor on the electrolytic properties of sulfide-conducting solid electrolytes

Solid solutions (SSs) based on CaYb 2 S 4 (Yb 3 S 4 structural type) and BaSm 2 S 4 (CaFe 2 O 4 structural type) were prepared using the ceramic and chemical methods for the preparation of oxide precursors. The samples were certified by XRD and electron microscopy. The electric conductivity and ther...

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Veröffentlicht in:Russian journal of electrochemistry 2015-05, Vol.51 (5), p.473-477
Hauptverfasser: Ananchenko, B. A., Mikhailichenko, T. V., Kalinina, L. A., Ushakova, Yu. N., Pentin, M. A., Myakishev, A. O.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Electrochemistry
Physical Chemistry
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Zusammenfassung:Solid solutions (SSs) based on CaYb 2 S 4 (Yb 3 S 4 structural type) and BaSm 2 S 4 (CaFe 2 O 4 structural type) were prepared using the ceramic and chemical methods for the preparation of oxide precursors. The samples were certified by XRD and electron microscopy. The electric conductivity and thermal stability of the samples were studied. The electron transport numbers were determined by the Hebb-Wagner method.
ISSN:1023-1935
1608-3342
DOI:10.1134/S102319351505002X