Molecular mobility of poly(vinylidene fluoride) in the anisotropic state

The effect of uniaxial orientational drawing and subsequent isometric annealing on the molecular mobility of poly(vinylidene fluoride) was studied by dielectric spectroscopy and dynamic mechanical analysis. The influence of orientation, the polymorphic composition of the crystalline phase, and the s...

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Veröffentlicht in:Polymer science. Series A, Chemistry, physics Chemistry, physics, 2008-03, Vol.50 (3), p.265-272
Hauptverfasser: Dmitriev, I. Yu, Gladchenko, S. V., Afanas’eva, N. V., Lavrent’ev, V. K., Bukošek, V., Baldrian, J., Elyashevich, G. K.
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Sprache:eng
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Zusammenfassung:The effect of uniaxial orientational drawing and subsequent isometric annealing on the molecular mobility of poly(vinylidene fluoride) was studied by dielectric spectroscopy and dynamic mechanical analysis. The influence of orientation, the polymorphic composition of the crystalline phase, and the structure of disordered regions on dielectric and mechanical relaxation in isotropic and oriented samples was investigated.
ISSN:0965-545X
1555-6107
DOI:10.1134/S0965545X08030048