Simulation of the formation of a single three-dimensional structural unit in free-radical polymerization

Simulation of the formation of a single three-dimensional structural unit in free-radical polymerization

Numerical experiments on the three-dimensional free radical polymerization of tetrafunctional monomers and oligomers were performed on a 100 × 100 × 100 cubic lattice by means of the Monte Carlo method. The effects of the initiation rate and the length of monomer molecule on the kinetic characterist...

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Veröffentlicht in:Polymer science. Series A, Chemistry, physics Chemistry, physics, 2008, Vol.50 (1), p.91-99
Hauptverfasser: Sivergin, Yu. M., Ismailov, R. R., Gaisin, F. R., Usmanov, S. M.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Modeling
Polymer Sciences
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Zusammenfassung:Numerical experiments on the three-dimensional free radical polymerization of tetrafunctional monomers and oligomers were performed on a 100 × 100 × 100 cubic lattice by means of the Monte Carlo method. The effects of the initiation rate and the length of monomer molecule on the kinetic characteristics of polymerization were investigated.
ISSN:0965-545X
1555-6107
DOI:10.1134/S0965545X08010148