Dynamics of macroscopic fluctuations in aqueous systems according to Rayleigh scattering data

The general question of the existence of macrofluctuations of physical characteristics of aqueous systems are discussed. Using the example of analyzing fluctuations in the Rayleigh scattering of natural untreated water, along with catholyte and anolyte obtained in its electrochemical treatment, the...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2015-09, Vol.89 (9), p.1693-1703
Hauptverfasser: Belovolova, L. V., Glushkov, M. V., Timashev, S. F.
Format: Artikel
Sprache:eng
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Zusammenfassung:The general question of the existence of macrofluctuations of physical characteristics of aqueous systems are discussed. Using the example of analyzing fluctuations in the Rayleigh scattering of natural untreated water, along with catholyte and anolyte obtained in its electrochemical treatment, the possibility of obtaining of quantitative information on the states and dynamics of changes in such systems is shown. Data on the parameters of oscillations in the Rayleigh light scattering of water catholyte and anolyte immediately after electrolysis, and one and two days after its completion, are presented. Calculations are performed using the general phenomenological approach to analyzing chaotic signals (flicker-noise spectroscopy). Quantitative characteristics that reveal substantial differences in the dynamics of macrofluctuations that develop in the catholyte and anolyte of the studied water are presented.
ISSN:0036-0244
1531-863X
DOI:10.1134/S003602441509006X