Frequency dispersion of the viscoelastic properties of solutions of electrolytes
Analytical expressions obtained earlier are used to numerically calculate the dynamic coefficients of the bulk η ν (ω) and shear η s (ω) viscosity and the corresponding modules of their bulk K (ω) and shear μ(ω) elasticity at a certain choice of the model of solution structure in an approximation of...
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Veröffentlicht in: | Russian Journal of Physical Chemistry A 2010-06, Vol.84 (6), p.954-959 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Analytical expressions obtained earlier are used to numerically calculate the dynamic coefficients of the bulk η
ν
(ω) and shear η
s
(ω) viscosity and the corresponding modules of their bulk
K
(ω) and shear μ(ω) elasticity at a certain choice of the model of solution structure in an approximation of the osmotic solution theory. The potential energy of the interaction between ions Φ
ab
(
r
) was taken as the sum of the Lennard-Jones potential and the generalized Debye potential, taking into account the configuration and size of ions. In this approximation, the viscoelastic properties of the NaCl water solution were numerically calculated over a wide interval of change in the thermodynamic parameters and frequency ranges. Satisfactory agreement with the literature experimental data was obtained. |
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ISSN: | 0036-0244 1531-863X |
DOI: | 10.1134/S0036024410060129 |