Elements of the topology of the region of the existence of the metastable states of a two-component vapor

Entire regions of the metastable states for binary and single-component systems were constructed. It was established that the regions include temperature intervals from absolute zero to critical temperatures, and from vapor—condensate equilibrium to the conditions of spinodal decomposition of supers...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2010-03, Vol.84 (3), p.364-369
Hauptverfasser: Anisimov, M. P., Fominykh, E. G., Akimov, S. V., Trilis, A. V.
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Sprache:eng
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Zusammenfassung:Entire regions of the metastable states for binary and single-component systems were constructed. It was established that the regions include temperature intervals from absolute zero to critical temperatures, and from vapor—condensate equilibrium to the conditions of spinodal decomposition of supersaturated vapor in the system. Algorithms for determining the regions of metastable states are presented. The data obtained on their basis are noted to coincide qualitatively with known results. Correlations found earlier are employed to calculate the critical pressures and temperatures for the binary systems in the study.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024410030040