Cobalt tetrasulfophthalocyaninate as a catalyst of the reduction of nitrite with thiourea dioxide

Cobalt tetrasulfophthalocyaninate as a catalyst of the reduction of nitrite with thiourea dioxide

The kinetics of reduction of nitrite with thiourea dioxide in the presence of cobalt tetrasulfophth-alocyaninate was studied. The process was shown to involve the Co II ↔ Co I catalytic cycle. The kinetic parameters of the reduction of Co II and Co I tetrasulfophthalocyaninates were determined

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2009-12, Vol.83 (12), p.2050-2053
Hauptverfasser: Pogorelova, A. S., Makarov, S. V., Ageeva, E. S., Silagi-Dumitresku, R.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Kinetics and Catalysis
Chemistry
Chemistry and Materials Science
Physical Chemistry
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Zusammenfassung:The kinetics of reduction of nitrite with thiourea dioxide in the presence of cobalt tetrasulfophth-alocyaninate was studied. The process was shown to involve the Co II ↔ Co I catalytic cycle. The kinetic parameters of the reduction of Co II and Co I tetrasulfophthalocyaninates were determined
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024409120085