Combined solubility of copper and zinc oxides in ammonia-ammonium solutions

The combined solubility of copper and zinc oxides was studied in ammonia-ammonium chloride solutions with mass fractions of ammonia of 2, 5, 10, 15, 20, and 25% and mass concentrations of ammonium chloride of 43.8, 110, 150, and 180 g/l (based on chloride ion) at 293.15, 303.15, 313.15, and 323.15 K...

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Veröffentlicht in:Russian Journal of Physical Chemistry A 2009-08, Vol.83 (8), p.1422-1425
Hauptverfasser: Peretrutov, A. A., Chubenko, M. N., Kim, P. P., Yakunin, Yu. I.
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Sprache:eng
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Zusammenfassung:The combined solubility of copper and zinc oxides was studied in ammonia-ammonium chloride solutions with mass fractions of ammonia of 2, 5, 10, 15, 20, and 25% and mass concentrations of ammonium chloride of 43.8, 110, 150, and 180 g/l (based on chloride ion) at 293.15, 303.15, 313.15, and 323.15 K. A eutonic type equilibrium was established in the systems, and the complex ions were mutually salted out.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024409080305