Photochemical reactions of di(naphthyl-1-methyl)mercury in various solvents
It was found that the photolysis of di(naphthyl-1-methyl)mercury ( 1 ) gives 1,2-dinaphthylethane ( 2 ) in heptane and benzene solvents and 2 and 1-methylnaphthalene in isopropanol and acetonitrile. Irradiation of 1 in carbon tetrachloride gives 2 and ClHgCH 2 C 10 H 7 as primary reaction products,...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2008, Vol.82 (1), p.119-121 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | It was found that the photolysis of di(naphthyl-1-methyl)mercury (
1
) gives 1,2-dinaphthylethane (
2
) in heptane and benzene solvents and
2
and 1-methylnaphthalene in isopropanol and acetonitrile. Irradiation of
1
in carbon tetrachloride gives
2
and ClHgCH
2
C
10
H
7
as primary reaction products, while the chloride is further photolyzed to
2
. Quantum yields of the photolysis of
1
are high and equal to unity almost for all solvents. The chloride photodecomposition yield is an order of magnitude lower (0.1). |
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| ISSN: | 0036-0244 1608-3415 1531-863X |
| DOI: | 10.1134/S0036024408010184 |