Thermolysis of binuclear heterometallic pivalate with Pd(II)-Ce(III) metal core in dibenzyl ether
A reaction between palladium(II) acetate and aqueous cerium(III) acetate in acetic acid with subsequent boiling in benzene with excess pivalic acid is found to yield the complex Pd(μ-OOCBu t ) 4 Ce(OOCBu t )(HOOCBu t ) 3 ( 1 ). The liquid-phase thermolysis of complex 1 in dibenzyl ether (190°C) lead...
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Veröffentlicht in: | Russian journal of inorganic chemistry 2014-07, Vol.59 (7), p.733-737 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | A reaction between palladium(II) acetate and aqueous cerium(III) acetate in acetic acid with subsequent boiling in benzene with excess pivalic acid is found to yield the complex Pd(μ-OOCBu
t
)
4
Ce(OOCBu
t
)(HOOCBu
t
)
3
(
1
). The liquid-phase thermolysis of complex
1
in dibenzyl ether (190°C) leads to the formation of the tetranuclear complex [Pd(μ-OOCBu
t
)
4
Ce(HOOCBu
t
)]
2
(μ-OOCBu
t
)(μ-OH
2
) (
2
). The structure of the synthesized complexes is established by X-ray diffraction. |
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ISSN: | 0036-0236 1531-8613 |
DOI: | 10.1134/S0036023614070171 |