Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, But, Ph)

We discovered that reactions of [Pd(OOCMe) 2 ] n and Pd 3 (μ-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz) 4 ](OOCMe) 2 , in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bond...

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Veröffentlicht in:	Russian journal of inorganic chemistry 2009, Vol.54 (9), p.1378-1389
Hauptverfasser:	Perova, E. V., Miloserdov, F. M., Yakovleva, M. A., Stolyarov, I. P., Nefedov, S. E.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Coordination Compounds Inorganic Chemistry
Online-Zugang:	Volltext
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