Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, But, Ph)

Effect of the nature of carboxylate anion on the features of intramolecular hydrogen bonding in [Pd(Hdmpz)4](OOCR)2 (R = Me, But, Ph)

We discovered that reactions of [Pd(OOCMe) 2 ] n and Pd 3 (μ-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz) 4 ](OOCMe) 2 , in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bond...

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Veröffentlicht in:Russian journal of inorganic chemistry 2009, Vol.54 (9), p.1378-1389
Hauptverfasser: Perova, E. V., Miloserdov, F. M., Yakovleva, M. A., Stolyarov, I. P., Nefedov, S. E.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Coordination Compounds
Inorganic Chemistry
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Zusammenfassung:We discovered that reactions of [Pd(OOCMe) 2 ] n and Pd 3 (μ-OOCMe) with 3,5-dimethylpyrazole (Hdmpz) yield mononuclear complex [Pd(Hdmpz) 4 ](OOCMe) 2 , in which acetate anions can exchange for pivalate or benzoate anions in reactions with proper acids. The specifics of intramolecular hydrogen bonding in the complexes prepared are discussed as dependent on the nature of the carboxylate anion using X-ray crystallography data.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023609090071