Synthesis, molecular and crystal structure, magnetic properties, luminescence, and solid-phase thermolysis of binuclear Ln(III) pivalates with 2,2′-dipyridyl and 1,10-phenanthroline molecules

Methods of synthesis of binuclear pivalate complexes L 2 Ln 2 (μ- O ,η 2 -OOCCMe 3 ) 2 (μ 2 - O , O ′-OOCCMe 3 ) 2 (η 2 -OOCCMe 3 ) 2 , where Ln = Sm, Eu, Gd, or Er and L = 2,2′-dipyridyl (Bipy) or 1,10-phenanthroline (Phen), from the corresponding binuclear complexes Ln 2 (μ 2 -OOCCMe 3 ) 4 (OOCCMe 3 ) 2 (HOOCCMe 3 ) 6 · HOOCCMe 3 ( I–IV ), as well as of coordination polymers {Ln(OOCCMe 3 ) 3 } n , were suggested. The compounds were characterized by X-ray crystallography and X-ray powder diffraction and their magnetic properties, solid-phase thermolysis, and the phase composition of solid decomposition products were studied. The structures of the metal carboxylate core and surrounding ligands were shown to have an effect on the thermal stability of the complexes. The luminescence properties of the Eu(III) complexes were analyzed.