Bimetallic Rh-Co/ZrO2 catalysts for ethanol steam reforming into hydrogen-containing gas

Bimetallic Rh-Co/ZrO2 catalysts for ethanol steam reforming into hydrogen-containing gas

The properties of supported bimetallic Rh-Co/ZrO 2 catalysts in ethanol steam reforming into hydrogen-containing gas were studied. The particles of Rh-Co solid solutions on the catalyst surface were prepared by the thermal decomposition of the double complex salt [Co(NH 3 ) 6 ][Rh(NO 2 ) 6 ] and the...

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Veröffentlicht in:Kinetics and catalysis 2010-12, Vol.51 (6), p.893-897
Hauptverfasser: Churakova, E. M., Badmaev, S. D., Snytnikov, P. V., Gubanov, A. I., Filatov, E. Yu, Plyusnin, P. E., Belyaev, V. D., Korenev, S. V., Sobyanin, V. A.
Format: Artikel
Sprache:eng
Schlagworte:
Catalysis
Chemistry
Chemistry and Materials Science
Physical Chemistry
Young Scientists’ School
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Zusammenfassung:The properties of supported bimetallic Rh-Co/ZrO 2 catalysts in ethanol steam reforming into hydrogen-containing gas were studied. The particles of Rh-Co solid solutions on the catalyst surface were prepared by the thermal decomposition of the double complex salt [Co(NH 3 ) 6 ][Rh(NO 2 ) 6 ] and the solid solution Na 3 [RhCo(NO 2 ) 6 ]. It was found that the bimetallic Rh-Co/ZrO 2 catalysts exhibited high activity in the reaction of ethanol steam reforming. The equilibrium composition of reaction products was attained at 500–700°C and a reaction mixture space velocity of 10000 h −1 .
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158410060157