Crystal structure and thermal stability of A μ1,1-(OMe)-bridged dimeric Schiff base iron(III) complex

Crystal structure and thermal stability of A μ1,1-(OMe)-bridged dimeric Schiff base iron(III) complex

A new μ 1,1 -OMe-bridged dimeric iron(III) complex, [Fe 2 L 2 (μ 1,1 -OMe) 2 (NCS) 2 ], where L is the deprotonated form of 2-[(2-ethylaminoethylimino)methyl]-5-methoxyphenol, has been prepared and structural characterized by elemental analysis, IR spectrum, and single crystal X-ray crystallography....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of structural chemistry 2014, Vol.55 (2), p.379-383
Hauptverfasser: Qian, S. -S., Wang, X., You, Z. -L., Zhu, H. -L.
Format: Artikel
Sprache:eng
Schlagworte:
Atomic
Atomic/Molecular Structure and Spectra
Brief Communications
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A new μ 1,1 -OMe-bridged dimeric iron(III) complex, [Fe 2 L 2 (μ 1,1 -OMe) 2 (NCS) 2 ], where L is the deprotonated form of 2-[(2-ethylaminoethylimino)methyl]-5-methoxyphenol, has been prepared and structural characterized by elemental analysis, IR spectrum, and single crystal X-ray crystallography. The complex crystallizes in the monoclinic space group P2 1 / c , with unit cell dimensions a = 10.156(1) Å, b = 11.972(1) Å, c = 14.256(2) Å, β = 102.643(3)°, V = 1691.3(3) Å 3 , Z = 2, R 1 = 0.0394, and wR 2 = 0.0922. Each Fe atom in the complex is in an octahedral coordination. The Fe...Fe distance is 3.102(1) Å. The thermal stability of the complex was studied.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476614020309