Unusual platinum complexes in the gas phase

Previously unknown cationic platinum complexes Pt(C 5 H 4 N)(C 5 H 5 N) + and Pt(C 5 H 4 N) + , where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-ch...

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Veröffentlicht in:Doklady. Physical chemistry (1991) 2016-05, Vol.468 (1), p.72-75
Hauptverfasser: Markov, A. A., Yakushev, I. A., Churakov, A. V., Stolyarov, I. P., Cherkashina, N. V., Kornev, A. B., Vargaftik, M. N., Gekhman, A. E., Moiseev, I. I.
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Sprache:eng
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Zusammenfassung:Previously unknown cationic platinum complexes Pt(C 5 H 4 N)(C 5 H 5 N) + and Pt(C 5 H 4 N) + , where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-chemical calculations.
ISSN:0012-5016
1608-3121
DOI:10.1134/S0012501616050031