Unusual platinum complexes in the gas phase
Previously unknown cationic platinum complexes Pt(C 5 H 4 N)(C 5 H 5 N) + and Pt(C 5 H 4 N) + , where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-ch...
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Veröffentlicht in: | Doklady. Physical chemistry (1991) 2016-05, Vol.468 (1), p.72-75 |
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Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | Previously unknown cationic platinum complexes Pt(C
5
H
4
N)(C
5
H
5
N)
+
and Pt(C
5
H
4
N)
+
, where platinum atom forms an unusual three-membered metallacycle with a deprotonated pyridine molecule, were detected in the gas phase by mass spectrometry and structurally characterized by DFT quantum-chemical calculations. |
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ISSN: | 0012-5016 1608-3121 |
DOI: | 10.1134/S0012501616050031 |