Photoinduced Polymerization of Solid C 60 Films

Photoinduced Polymerization of Solid C 60 Films

The irradiation of oxygen-free, face-centered-cubic C 60 films with visible or ultraviolet light phototransformed C 60 into a different solid phase. Results from laser desorption mass spectroscopy, scanning electron microscopy, Raman and infrared spectroscopy, optical absorption, and luminescence in...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 1993-02, Vol.259 (5097), p.955-957
Hauptverfasser: Rao, A. M., Zhou, Ping, Wang, Kai-An, Hager, G. T., Holden, J. M., Wang, Ying, Lee, W.-T., Bi, Xiang-Xin, Eklund, P. C., Cornett, D. S., Duncan, M. A., Amster, I. J.
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Sprache:eng
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Zusammenfassung:The irradiation of oxygen-free, face-centered-cubic C 60 films with visible or ultraviolet light phototransformed C 60 into a different solid phase. Results from laser desorption mass spectroscopy, scanning electron microscopy, Raman and infrared spectroscopy, optical absorption, and luminescence indicate that a photopolymerization of the fullerene molecules within the film occurred.
ISSN:0036-8075
1095-9203
DOI:10.1126/science.259.5097.955