Working Fluid Selection and Thermodynamic Optimization of the Novel Renewable Energy-Based RESTORE Seasonal Storage Technology

Seasonal-based energy storage is expected to be one of the main options for the decarbonization of the space heating sector by increasing the renewables dispatchability. Technologies available today are mainly based on hot water and can only partially fulfill the efficiency, energy density and affordability requirements. This work analyzes a novel system based on pumped thermal energy storage (PTES) concept to maximize renewables and waste heat exploitation during summer and make them available during winter. Organic fluid-based cycles are adopted for the heat upgrade during hot season (heat pump (HP)) and to produce electricity and hot water during cold season (power unit (PU)). Upgraded thermal energy drives an endothermic reaction producing dehydrated solid salts, which can be stored for months using inexpensive and high energy density solutions. This paper focuses on thermodynamic cycles design, comparing the performance attainable with several working fluids. Two different configurations are investigated: coupled systems, sharing the fluid and heat exchangers in both operating modes, and decoupled systems. A preliminary economic assessment completes the study, including a sensitivity analysis on electricity and heat prices. Cyclopentane is identified as a promising working fluid for coupled systems, reaching competitive round trip efficiencies (RTEs), maximizing the ratio between performance and HX surfaces, without excessive turbomachinery volume ratios and volumetric flows. Economic analysis shows that solutions with lower efficiency, but also lower capital cost, can achieve competitive payback times (PBT). On the contrary, decoupled systems are less attractive, as they reach slightly higher thermodynamic performance, but require higher capital costs, possibly being of interest only in specific applications.