Photoluminescence Properties of Er/Pr‐Doped K 0.5 Na 0.5 NbO 3 Ferroelectric Ceramics

Er/Pr‐doped K 0.5 Na 0.5 NbO 3 ceramics have been fabricated and the effects of Pr 3+ on their photoluminescence properties have been investigated systematically. The visible upconversion emissions, near‐infrared and mid‐infrared downconversion emissions of Er 3+ ions under the excitation of 980 nm...

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Veröffentlicht in:Journal of the American Ceramic Society 2015-07, Vol.98 (7), p.2139-2145
Hauptverfasser: Wu, Xiao, Lau, Chi Man, Kwok, Kin Wing
Format: Artikel
Sprache:eng
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Zusammenfassung:Er/Pr‐doped K 0.5 Na 0.5 NbO 3 ceramics have been fabricated and the effects of Pr 3+ on their photoluminescence properties have been investigated systematically. The visible upconversion emissions, near‐infrared and mid‐infrared downconversion emissions of Er 3+ ions under the excitation of 980 nm have been studied in detail. The effects of Pr 3+ on PL properties and energy‐transfer processes have also been elucidated. By selecting an appropriate excitation source, simultaneous visible downconversion emissions of Er 3+ and Pr 3+ ions can be realized, and the emission colors of the ceramics can be tuned via the concentration of Pr 3+ ions in a wide range from yellowish green to yellow. Our results also reveal that the photoluminescence emissions of the ceramics can be enhanced by the alignment of polarization of the ferroelectric host.
ISSN:0002-7820
1551-2916
DOI:10.1111/jace.13605