Electrochemical C-V profiling of heterojunction device structures

Electrochemical capacitance-voltage profiles of multiple (In,Al) GaAs heterostructures have been measured and compared with the results of a numerical calculation of the apparent charge density based on a one-dimensional Poisson solver. The calculation, using layer thicknesses, dopings, and heterojunction band discontinuities obtained from MBE growth calibrations, is in overall agreement with the measured data. The largest discrepancy occurs between the expected and measured heterojunction band discontinuity. This difference is consistent with an electrolyte/semiconductor interface which is not planar on a scale comparable to the layer thickness.< >